SIB-1893
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识别信息 | |
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CAS号 | 7370-21-0(trans) ![]() 6266-99-5 ![]() |
PubChem CID |
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ChEMBL |
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CompTox Dashboard(英语:CompTox Chemicals Dashboard) (EPA) |
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化学信息 | |
化学式 | C14H13N |
摩尔质量 | 195.27 g·mol−1 |
3D模型(JSmol(英语:JSmol)) |
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SIB-1893是一种有机化合物,化学式为C14H13N。它可由2-甲基-6-苯乙炔基吡啶和硫化钠九水合物在二甲基甲酰胺中于140 °C反应制得。[1]以苯甲醛和2,6-二甲基吡啶为原料在路易斯酸催化下反应,也可得到该化合物。[2]在草酸二水合物的存在下,它可以发生光二聚反应,得到1,3-二苯基-2,4-二(6-甲基吡啶-2-基)环丁烷。[3]
参考文献
- ^ Zhengwang Chen, Miaoting Luo, Yuelu Wen, Guotian Luo, Liangxian Liu. Transition-Metal-Free Semihydrogenation of Diarylalkynes: Highly Stereoselective Synthesis of trans -Alkenes Using Na 2 S·9H 2 O. Organic Letters. 2014-06-06, 16 (11): 3020–3023 [2021-09-21]. ISSN 1523-7060. doi:10.1021/ol501137x. (原始内容存档于2021-09-21) (英语).
- ^ Dan Mao, Gang Hong, Shengying Wu, Xin Liu, Jianjun Yu, Limin Wang. Lewis-Acid-Catalyzed Benzylic Reactions of 2-Methylazaarenes with Aldehydes: Benzylic Reactions of 2-Methylazaarenes. European Journal of Organic Chemistry. 2014-05, 2014 (14): 3009–3019 [2021-09-21]. doi:10.1002/ejoc.201400073 (英语).
- ^ Thanh Binh Nguyen, Tuan Minh Nguyen, Pascal Retailleau. [2+2] Photodimerization of Stilbazoles Promoted by Oxalic Acid in Suspension. Chemistry – A European Journal. 2020-04-09, 26 (21): 4682–4689 [2021-09-21]. ISSN 0947-6539. doi:10.1002/chem.201905597 (英语).