Lithium orthosilicate
Chemical compound
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ECHA InfoCard | 100.033.290 ![]() |
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Chemical formula | Li4O4Si |
Molar mass | 119.84 g·mol−1 |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references |
Chemical compound
Lithium orthosilicate is a compound with the chemical formula Li4SiO4. It is a white ceramic compound, which melts congruently at a temperature of 1,258 °C (2,296 °F).[1]
Lithium orthosilicate is of primary interest towards carbon dioxide capture, as this compound reacts with CO2 at elevated temperatures to form lithium carbonate, and has been implemented in limited scale in such applications.[2] Further applications of Li4SiO4 include solid electrolytes for lithium-ion batteries, specifically solid state batteries,[3] and tritium breeding materials, as a component of the breeding blanket for planned fusion energy systems such as ITER.[1]
See also
- Lithium metasilicate — other lithium silicate compound
- Carbon dioxide scrubber
References
- ^ a b Hanaor, D. A. H.; Kolb, M. H. H.; Gan, Y.; Kamlah, M.; Knitter, R. (2014). "Solution based synthesis of mixed-phase materials in the Li2TiO3-Li4SiO4 system". Journal of Nuclear Materials. 456: 151–161. arXiv:1410.7128. Bibcode:2015JNuM..456..151H. doi:10.1016/j.jnucmat.2014.09.028. S2CID 94426898.
- ^ Optimization of Li4SiO4 synthesis conditions by a solid state method for maximum CO2 capture at high temperature
- ^ Thin Film Lithium Battery using Stable Solid Electrolyte Li4SiO4 Fabricated by PLD
- v
- t
- e
- Li2
- LiAlCl4
- Li1+xAlxGe2−x(PO4)3
- LiAlH4
- LiAlO2
- LiAl1+xTi2−x(PO4)3
- LiAs
- LiAsF6
- Li3AsO4
- LiAt
- Li[AuCl4]
- LiB(C2O4)2
- LiB(C6F5)4
- LiWF6
- LiBF4
- LiBH4
- LiBO2
- LiB3O5
- Li2B4O7
- LiAsF6
- Li2SnF6
- Li2TiF6
- Li2ZrF6
- Li2B4O7·5H2O
- LiBSi2
- LiBr
- LiBr·2H2O
- LiBrO
- LiBrO2
- LiBrO3
- LiBrO4
- Li2C2
- LiCF3SO3
- CH3CH(OH)COOLi
- LiC2H2ClO2
- LiC2H3IO2
- Li(CH3)2N
- LiCHO2
- LiCH3O
- LiC2H5O
- LiCN
- Li2CN2
- LiCNO
- Li2CO3
- Li2C2O4
- LiCl
- LiCl·H2O
- LiClO
- LiFO
- LiClO2
- LiClO3
- LiClO4
- LiCoO2
- Li2CrO4
- Li2CrO4·2H2O
- Li2Cr2O7
- CsLiB6O10
- LiD
- LiF
- Li2F
- LiF4Al
- Li3F6Al
- FLiBe
- LiFePO4
- FLiNaK
- LiGaH4
- Li2GeF6
- Li2GeO3
- LiGe2(PO4)3
- LiH
- LiH2AsO4
- Li2HAsO4
- LiHCO3
- Li3H(CO3)2
- LiH2PO3
- LiH2PO4
- LiHSO3
- LiHSO4
- LiHe
- LiI
- LiIO
- LiIO2
- LiIO3
- LiIO4
- Li2IrO3
- Li7La3Zr2O12
- LiMn2O4
- Li2MoO4
- Li0.9Mo6O17
- LiN3
- Li3N
- LiNH2
- Li2NH
- LiNO2
- LiNO3
- LiNO3·H2O
- Li2N2O2
- LiNa
- Li2NaPO3
- LiNaNO2
- LiNbO3
- Li2NbO3
- LiO−
- LiO2
- LiO3
- Li2O
- Li2O2
- LiOH
- Li3P
- LiPF6
- Li3PO4
- Li2HPO3
- Li2HPO4
- Li3PO3
- Li3PO4
- Li2Po
- Li2PtO3
- Li2RuO3
- Li2S
- LiSCN
- LiSH
- LiSO3F
- Li2SO3
- Li2SO4
- Li[SbF6]
- Li2Se
- Li2SeO3
- Li2SeO4
- LiSi
- Li2SiF6
- Li4SiO4
- Li2SiO3
- Li2Si2O5
- LiTaO3
- Li2Te
- LiTe3
- Li2TeO3
- Li2TeO4
- Li2TiO3
- Li4Ti5O12
- LiTi2(PO4)3
- LiVO3·2H2O
- Li3V2(PO4)3
- Li2WO4
- LiYF4
- LiZr2(PO4)3
- Li2ZrO3
- Hemolithin (extraterrestrial protein)
- Organolithium reagents
- CH3COOLi
- C4H6LiNO4
- LiC2F6NO4S2
- LiN(SiMe3)2
- Li3C6H5O7
- C5H5Li
- LiN(C3H7)2
- (C6H5)2PLi
- C18H35LiO3
- C6H13Li
- C4H9Li
- CH3CHLiCH2CH3
- (CH3)3CLi
- C12H28BLi
- CH3Li
- Li+C10H8−
- C5H11Li
- C5H3LiN2O4
- C6H5Li
- LiC2CH3
- LiO2C(CH2)16CH3
- C4H5LiO4
- LiEt3BH
- LiOC(CH3)3
- C9H18LiN
- LiC2H3 Vinyllithium
- LiC
11H
23COO
- Amblygonite
- Berezanskite
- Brannockite
- Cryolithionite
- Darapiosite
- Darrellhenryite
- Elbaite
- Fluorine Elbaite
- Fluor-liddicoatite
- Emeleusite
- Eucryptite LiAlSiO4
- Faizievite
- Hectorite
- Hsianghualite
- Jadarite LiNaSiB3O7OH
- Keatite Li(AlSi2O6)
- Kunzite
- Lavinskyite
- Lepidolite
- Lithiophilite LiMnPO4
- Lithiophosphate Li3PO4
- Manandonite
- Manganoneptunite
- Nambulite
- Neptunite
- Olympite
- Petalite LiAlSi4010
- Pezzottaite Cs(Be2Li)Al2Si6O18
- Rossmanite
- Saliotite
- Sogdianite
- Spodumene LiAl(SiO3)2
- Sugilite
- Tiptopite
- Tourmaline
- Triphylite LiFePO4
- Zabuyelite Li2CO3
- Zektzerite
- Zinnwaldite
- LixBey
- HLiHe+
- LiFHeO
- LiHe2
- (HeO)(LiF)2
- La2/3-xLi3xTiO3He
- Aluminium–lithium alloys
- Heteroatom-promoted lateral lithiation
- LB buffer
- Lithium atom
- Lithium medication
- LiNixCoyAlzO2
- LiNixMnyCozO2
- Lithium soap
- Lithium Triangle
- Lucifer yellow
- Magnesium–lithium alloys
- NASICON
- Environmentally friendly red light flare